Photos of Angelina Jolie almost without makeup while dressed in jeans and simple sleeveless top during her wedding to Bill Bob Thornton in 2000 have emerged.

"The casual pair look more like they have just walked off a movie set to pose with a fan rather then tied the knot in what became one of Hollywood's most notorious marriages," Daily Mail described the former lead star of the "Lara Croft: Tomb Raider" series and her former husband.

The Daily Mail reported that the two "collectively chalked up nine marriages" between them and that they separated two years after getting married. They had their divorce finalized in 2003.

Reverend Jim Hamilton, who married the couple 15 years ago, shared the photos of the nuptials. The ceremony was very simple as can be seen in Bill Bob Thornton and Angelina Jolie's outfits. Plus there's the fact that Brad Pitt's current wife was almost without makeup.

The reverend said he "is praying the wild pair has settled down for good this time".

"I'm very happy for them that they've both happily married again. I am glad to hear Billy Bob has married again, of course everybody knew about Angelina and Brad," Rev. Hamilton said.

"I was glad Angelina married Brad, I like Brad Pitt, his movies and he's a real decent human being and she is, too."

The cleric shared he hopes that their present marriages will already be their last.

"I hope they both have very long and happy marriages and congratulate them both. I hope this is the last one for both of them and they have found their true soulmates this time," he said.

At present, the 39-year-old actress is married to American actor and producer Brad Pitt for seven months already. Meanwhile, the 59-year-old actor, director and musician got hitched with his long-time girlfriend Connie Angland in October 2014, two months after the "Brangelina" wedding.

"Personally I don't think they had really planned it out for long, I think it was a spur of the moment deal but I'm not sure, I didn't ask "oh what made you decide to get married?" It was my job to marry them," Rev. Hamilton said.